Bis[μ-N,N′-bis(2,6-diisopropylphenyl)ethene-1,2-diamido]-1,4(η2);1:2κ4N:N;3:4κ4N:N-bis(diethyl ether)-1κO,4κO-di-μ-hydrido-2:3κ4H:H-2,3-dichromium(II)-1,4-dilithium(I) pentane hemisolvate
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چکیده
منابع مشابه
Bis[μ-N,N′-bis(2,6-diisopropylphenyl)ethene-1,2-diamido]-1,4(η2);1:2κ4 N:N;3:4κ4 N:N-bis(diethyl ether)-1κO,4κO-di-μ-hydrido-2:3κ4 H:H-2,3-dichromium(II)-1,4-dilithium(I) pentane hemisolvate
The title compound, [Cr(2)Li(2)(C(26)H(36)N(2))(2)(μ-H)(2)(C(4)H(10)O)(2)]·0.5C(5)H(12), is a binuclear chromium complex bridged by two hydrogen atoms. Each chromium atom is coordinated in a distorted square-planar geometry by one chelating bis-(2,6-diisopropyl-phen-yl)ethene-1,2-diamido ligand via its two N atoms. Additionally, two diametrically opposed lithium ether adducts coordinate in an η...
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The half-sandwich title compound, [Yb(2)(C(13)H(21))(2)I(2)(C(4)H(10)O)(2)], crystallizes as a centrosymmetric dimer. The Yb atom is coordinated in a three-legged piano-stool geometry by a cyclo-penta-dienyl ring, two I anions and the O atom of a diethyl ether mol-ecule. The central Yb(2)I(2) core is an approximate square.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s160053681000560x